CO2基聚脲多孔材料对甲基橙吸附性能研究

崔萌, 曾金铃, 董希洋, 谷潇夏, 张秀芹

化工新型材料 ›› 2021, Vol. 49 ›› Issue (11) : 211 -216.

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化工新型材料 ›› 2021, Vol. 49 ›› Issue (11) : 211-216. DOI: 10.19817/j.cnki.issn 1006-3536.2021.11.044
科学研究

CO2基聚脲多孔材料对甲基橙吸附性能研究

    崔萌, 曾金铃, 董希洋, 谷潇夏, 张秀芹
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Adsorption capacity of CO2-based polyurea porous material for methyl orange

  • Cui Meng, Zeng Jinling, Dong Xiyang, Gu Xiaoxia, Zhang Xiuqin
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摘要

为了有效地去除印染废水中甲基橙(MO)等合成染料,以CO2和1,6-己二胺为原料,采用无催化剂、无脱水剂法制备了CO2基聚脲(CO2-PU)多孔材料,并对材料进行表征,研究了CO2-PU对MO的吸附性能和机理。结果表明:CO2-PU对MO具有良好的吸附性能,当pH为4,吸附时间为20min时,5mg CO2-PU对MO的吸附率和吸附量分别能达到96.4%和96.4mg/g,并且CO2-PU具有良好的循环使用性能。CO2-PU对MO的吸附过程符合准二级动力学模型,吸附行为与Langmuir吸附等温线模型一致。

Abstract

In order to effectively remove methyl orange (MO) and other synthetic dyes from dyeing wastewater,CO2-based polyurea (CO2-PU) porous materials were prepared using CO2 and 1,6-hexanediamine as raw materials without catalyst and dehydrating agent.The materials were characterized,and the adsorption capacity and mechanism of CO2-PU for MO were investigated.The results showed that CO2-PU had good adsorption performance for MO.When the pH was 4 and the adsorption time was 20min,the adsorption efficiency and adsorption capacity of 5mg CO2-PU for MO could reach 96.4% and 96.4mg/g,respectively,and had good recycling performance.The adsorption process of CO2-PU for MO conformed to the pseudo-second-order kinetic model.The adsorption behavior was consistent with the Langmuir adsorption isotherm model.

关键词

二氧化碳 / 聚脲 / 多孔聚合物 / 吸附 / 染料

Key words

carbon dioxide / polyurea / porous polymer / adsorption / dye

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CO2基聚脲多孔材料对甲基橙吸附性能研究[J]. 化工新型材料, 2021, 49(11): 211-216 DOI:10.19817/j.cnki.issn 1006-3536.2021.11.044

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基金资助

北京服装学院高水平教师队伍建设专项资金资助项目(BIFTXJ201924);北京市教育委员会科研计划项目资助(KM202110012005);北京市长城学者培育计划(CTT&TCD20180321)

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